✦ LIBER ✦

A criterion from vibrational spectra for distinguishing the N2H+5 from the N2H2+6 ion: vibrational spectra of hydrazinium (1+) and (2+) fluorometalates and Raman spectra of hydrazinium (1+) and (2+) fluorides in the 900–1700 cm−1 region

✍ Scribed by Svetozar Milićev; Jadran Maček

Publisher: Elsevier Science
Year: 1985
Tongue: English
Weight: 383 KB
Volume: 41
Category: Article
ISSN: 1386-1425
DOI: 10.1016/0584-8539(85)80170-7

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✦ Synopsis

The sole dependable criterion is the activity of this vibration which appears in N,Hi+ compounds only in the Raman and in N,Hl compounds both in the Raman and the i.r. independent of ion conformation. Multiple N-H deformation and rocking absorptions reflect solid state interactions in fluorometalates, but as no strong hydrogen bonds were observed, their high position, comparable with fluorides, seems to be caused by some other effects. An exolanation for the hieh freauencv of the N-N stretching absorption in the spectra of coordinated N,H: ion is offered.

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