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Vibrational spectra and structure of tetracyclopentadienyl derivatives of zirconium and hafnium

✍ Scribed by B. V. Lokshin; É. M. Brainina


Publisher
SP MAIK Nauka/Interperiodica
Year
1972
Tongue
English
Weight
384 KB
Volume
12
Category
Article
ISSN
0022-4766

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## The (trimetaphosphimato)hafnates and -zirconates Na 4 {Hf 4 (µ 4 -O)(µ-OH) 6 [(PO 2 NH) ), c = 50.284(10) A ˚, Z = 6] were obtained by the stoichiometric reaction of HfOCl 2 • 8 H 2 O and ZrOCl 2 • 8 H 2 O with an aqueous solution of Na 3 (PO 2 NH) 3 • 4 H 2 O, followed by the diffusion-control