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Ir and PMR spectra and structure of zirconium and hafnium borohydrides

โœ Scribed by V. V. Volkov; E. V. Sobolev; E. E. Zaev; O. I. Shapiro


Publisher
SP MAIK Nauka/Interperiodica
Year
1968
Tongue
English
Weight
272 KB
Volume
8
Category
Article
ISSN
0022-4766

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## The (trimetaphosphimato)hafnates and -zirconates Na 4 {Hf 4 (ยต 4 -O)(ยต-OH) 6 [(PO 2 NH) ), c = 50.284(10) A หš, Z = 6] were obtained by the stoichiometric reaction of HfOCl 2 โ€ข 8 H 2 O and ZrOCl 2 โ€ข 8 H 2 O with an aqueous solution of Na 3 (PO 2 NH) 3 โ€ข 4 H 2 O, followed by the diffusion-control