✦ LIBER ✦

Vibrational spectra and Raman intensity of Cd(CN)2·CCl4 clathrate

✍ Scribed by Isao Kanesaka; Tomomi Tamura; Youta Akizawa

Publisher: John Wiley and Sons
Year: 1999
Tongue: English
Weight: 112 KB
Volume: 30
Category: Article
ISSN: 0377-0486
DOI: 10.1002/(sici)1097-4555(199901)30:1<69::aid-jrs344>3.0.co;2-t

No coin nor oath required. For personal study only.

✦ Synopsis

The infrared and Raman spectra of clathrate are reported. A normal coordinate analysis and a Cd(CN) 2 AE CCl 4 Raman intensity analysis on the basis of the modiÐed many-body model were carried out to clarify the assignments of the observed bands and to examine the intensity changes of the four vibrational modes of on going from CCl 4 gaseous to the clathrate. It was found that the Raman intensity of of is relatively enhanced in the CCl 4 m 1 CCl 4 clathrate compared with the gaseous state. This is explained in terms of the many-body model. The phase transition was found at 220 K, which is ascribed to ordering of molecules, although it is not clear whether the phase CCl 4 transition is of Ðrst or second order.

📜 SIMILAR VOLUMES

Vibrational spectra and Raman intensity

Vibrational spectra and Raman intensity of N(CH3)4[CdCu(CN)4]·CCl4 clathrate

✍ Isao Kanesaka; Junko Kitamura; Shin-ichi Nishikiori 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 84 KB 👁 1 views

The Raman and infrared spectra of N(CH 3 ) 4 [CdCu(CN) 4 ]•CCl 4 are reported, revealing back-donation of the d electrons of Cu Y ions to C N bonds, a Raman intensity change, especially in the n 2 mode of CCl 4 , and the existence of strong host modes at 170 and 143 cm -1 . A normal coordinate analy

ChemInform Abstract: Preparation, Crysta

ChemInform Abstract: Preparation, Crystal Structures, Vibrational Spectra, and Normal Coordinate Analysis of [(Mo6Br8i)Y6o] 2-; Yo: CN, NCS.

✍ M. K. SIMSEK; D. BUBLITZ; W. PREETZ 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 38 KB

Preparation, Crystal Structures, Vibrational Spectra, and Normal Coordinate Analysis of [(Mo 6 Br 8 i )Y 6 o ] 2-; Y o : CN, NCS. -Single crystal XRD of (IV) shows a triclinic structure (space group P1, Z = 1) while (II) has a monoclinic structure (P2 1 /n, Z = 2). By use of the molecular parameters

ChemInform Abstract: Synthesis, 11B NMR

ChemInform Abstract: Synthesis, 11B NMR and Vibrational Spectra of Mononitrooctahydro-closo-nonaborate(2-) and Monoaminooctahydro-closo-nonaborate(2-) and Crystal Structure of (Ph4P)2 [1-(NO2)B9H8]×CH3CN.

✍ K. Siegburg; W. Preetz 📂 Article 📅 2000 🏛 John Wiley and Sons ⚖ 38 KB

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

ChemInform Abstract: Crystal Structure,

ChemInform Abstract: Crystal Structure, Electronic Structure, and Temperature-Dependent Raman Spectra of Tl[Ag(CN)2]: Evidence for Ligand-Unsupported Argentophilic Interactions.

✍ M. A. OMARY; T. R. WEBB; Z. ASSEFA; G. E. SHANKLE; H. H. PATTERSON 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 34 KB