ChemInform Abstract: Preparation, Crystal Structures, Vibrational Spectra, and Normal Coordinate Analysis of [(Mo6Br8i)Y6o] 2-; Yo: CN, NCS.

✍ Scribed by M. K. SIMSEK; D. BUBLITZ; W. PREETZ

• Publisher: John Wiley and Sons
• Year: 2010
• Weight: 38 KB
• Volume: 29
• Category: Article
• ISSN: 0931-7597
• DOI: 10.1002/chin.199813002

✦ Synopsis

Preparation, Crystal Structures, Vibrational Spectra, and Normal Coordinate Analysis of [(Mo 6 Br 8 i )Y 6 o ] 2-; Y o : CN, NCS. -Single crystal XRD of (IV) shows a triclinic structure (space group P1, Z = 1) while (II) has a monoclinic structure (P2 1 /n, Z = 2). By use of the molecular parameters from the X-ray analysis the 10 K IR and Raman spectra of the (Bu 4 N) cluster salts are assigned by normal coordinate analyses based on a modified valence force field. -(SIMSEK, M.