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Vibrational spectra and dispersion curves of poly-L-proline II chain

✍ Scribed by V. D. Gupta; R. D. Singh; A. M. Dwivedi

Publisher: Wiley (John Wiley & Sons)
Year: 1973
Tongue: English
Weight: 379 KB
Volume: 12
Category: Article
ISSN: 0006-3525
DOI: 10.1002/bip.1973.360120613

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✦ Synopsis

Abstract

Using Wilson's GF‐matrix method as modified by Higgs for infinite helical polymers, dispersion curves and the frequency distribution function have been calculated for poly‐L‐proline II chain. Infrared spectrum is obtained and a Urey‐Bradley force field, which provides best fit with the observed frequencies, is evaluated. The result are discussed from the viewpoint of the conformational characteristics of forms I and II.

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