Rate constants have been determined at (298 \* 4) K for the reactions: and the relaxation processes: (lb) HF(u = 1) + HCN -HF(v = 0) + HCN Time-resolved HF(1,O) emission was observed following the photolysis of Fz with pulses from an excimer laser operating on XeCl ( h = 308 nm). Analysis of the
Vibrational relaxation rate of HF(2) by HF
β Scribed by Cohen, N. ;Bott, J. F.
- Book ID
- 115324753
- Publisher
- The Optical Society
- Year
- 1976
- Tongue
- English
- Weight
- 589 KB
- Volume
- 15
- Category
- Article
- ISSN
- 1559-128X
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The relaxation rams of u = 3 and u = 4 were determined to be k\* = (2.8 i-0.4) X IO-" cm3 molecule-t SC' and k$ = (7.2 + 05) X lo-" cm3 molecule-t SC' at 293 K. It is shown that single quantum energy transfer can account for all of rhe nirational relaxation.
## Abstract The rate of vibrational relaxation of HF(__v__ = 1) by F atoms has been calculated using quasiβclassical trajectory techniques. An attempt has been made to account for the effects of multiple potential energy surfaces on the vibrational relaxation efficiency within the electronically ad