Vibrational relaxation of the ν2=1 level of ortho and para NH3
✍ Scribed by Danagher, D. J.; Reid, J.
- Book ID
- 120185673
- Publisher
- American Institute of Physics
- Year
- 1987
- Tongue
- English
- Weight
- 838 KB
- Volume
- 86
- Category
- Article
- ISSN
- 0021-9606
- DOI
- 10.1063/1.452569
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Line positions and line intensities of the nu1, nu3, and 2nu4 bands of 14NH3 were analyzed using line positions from 0.0054 cm-1 apodized resolution FT spectra recorded at Orsay and using line intensities from 0.011 cm-1 unapodized resolution FT spectra recorded at Kitt Peak National Observatory. Ab
The.viirational r&xation of ortho-para-H2 mixtures :vas studied in the interval 400-50 K. At and above 300 K the ortho and para self-relaxation rates, .koo and kpb, tie identical within experimental error. In the low temgerature range, .koo > kpP and k,, is found to vary slowly with temperature.