Vibrational relaxation of the CO2 lower laser level by H2O
โ Scribed by K. Bulthuis; G.J. Ponsen
- Publisher
- Elsevier Science
- Year
- 1971
- Tongue
- English
- Weight
- 144 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0375-9601
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
The saturation of the ruhsr\tion rate of the 100 vibmtionnl levei of CO2 for larger Hz0 and I;20 densities is esplained by the energy eschsnge between. the 100 and 01'0 vibrational le~ls, giving a rate constant of4 X lo-I3 cm3 set-' for t-his procas.
Vibrational relasatioo of CO2 by Hz0 has been studied theoretiully. Earlier theoretical works are critically analyzed. A new mechanism of V-R-T interaction is put forxvard and a functional equation for the probability factor is obtained. Collisions of CO2 with H-J 0 adsorbed on a solid surface are
The vibrational relasation time for COz(v3) + O(3P) has been mcasurcd by Inscr fluorescence. The observed value, pCo2,0 = 0.21 \* 0.04 fiscc, is an order of mqniludc lower than the relaxation time for self-collisions.