Vibrational relaxation of D2 in collisions with He in the range 400—80 K
✍ Scribed by Jacques Lukasik
- Publisher
- Elsevier Science
- Year
- 1976
- Tongue
- English
- Weight
- 164 KB
- Volume
- 44
- Category
- Article
- ISSN
- 0009-2614
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📜 SIMILAR VOLUMES
The vibrational relaxation of ortho-para-Hz in collisions with 4He has been studied in the interval 300-50 K. At 300 K the ortho Hz -He and para Hz-He rates are identical within experimental error. In the low temperature range ko~z\_~e
The.viirational r&xation of ortho-para-H2 mixtures :vas studied in the interval 400-50 K. At and above 300 K the ortho and para self-relaxation rates, .koo and kpb, tie identical within experimental error. In the low temgerature range, .koo > kpP and k,, is found to vary slowly with temperature.
Cross secfiws and rate constants for the vibrat$onal Maxation of H&J = I,i= I) in collisions with 4He were determined using the coupled states method with a fulIy-converged channel basis. The interaction potential was taken to be that of Gordon and Secrest with the elastic matrix elements modified t