have been performed with the laser excited fluorescence method of the rates of vibratianal drcrctivation of the upper CO2 laser level by ONF, COF;? and 03. In each cast, rapid near-resonant V + V transfer deactivation mechanisms are indicated.
Vibrational relaxation of CO2(00°1) and N2O(00°1) by NO
✍ Scribed by F. Al Adel; L. Doyennette; M. Margottin-Maclou; L. Henry
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- English
- Weight
- 630 KB
- Volume
- 74
- Category
- Article
- ISSN
- 0301-0104
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Vibrational relasatioo of CO2 by Hz0 has been studied theoretiully. Earlier theoretical works are critically analyzed. A new mechanism of V-R-T interaction is put forxvard and a functional equation for the probability factor is obtained. Collisions of CO2 with H-J 0 adsorbed on a solid surface are
The rake constam [or NO+(u) vibrational relaxation by memsrable 02('A ) molecul& is round LO be (3+2)x10-" err? 5-l al room lemperanxc. in comras~ IO the lack of vibrational quenching of NO'(u) by ground-stale 02('X) molecules. [or which the quenching mLe constant <lo-" cm3 s-l. This suggests that N
The infrared emission observed from Hz0 or Co, when added to discharged oxygen containing Oz(r Zg> and C&(lA ) is shown to arise from their vibrational excitation in the quenching of Oz(\* $'). There was no ev&nce that O$'X> is quenched to the ground state rather than to the ' 4 state.