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Vibrational relaxation of CO 2 (ν 2 ) by atomic oxygen

✍ Scribed by Castle, Karen J.; Kleissas, Katherine M.; Rhinehart, Justin M.; Hwang, Eunsook S.; Dodd, James A.

Book ID
119670057
Publisher
American Geophysical Union
Year
2006
Tongue
English
Weight
392 KB
Volume
111
Category
Article
ISSN
0148-0227

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Vibrational relaxation of NO(ν = 2, 3) b
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A two-laser, pump-probe arrangement has been used to measure room-temperature rate constants for the collision-induced relaxation of NO(v ~ 2, 3) by O atoms. The rate constants ko(o) are equal to (2.2 + 0.2) × 10-~t and (2.5 + 0.3) x 10 -11 cm 3 s -1 for v = 2 and 3, respectively. These values are s

Vibrational relaxation of CO2(v3) by O a
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✍ J.H.W. Cramp; J.D. Lambert 📂 Article 📅 1973 🏛 Elsevier Science 🌐 English ⚖ 334 KB

The vibrational relasation time for COz(v3) + O(3P) has been mcasurcd by Inscr fluorescence. The observed value, pCo2,0 = 0.21 \* 0.04 fiscc, is an order of mqniludc lower than the relaxation time for self-collisions.