A tunable dye laser was used to populate selectively a single rotational-vibrational state of N 2 ( B 'E , u' = 0, N' = O-l 5 ) . The population changes induced by collisions with He were determined using time-resolved spectroscopy in a flowing afterglow experiment. Total rotational transfer rates f
✦ LIBER ✦
Vibrational relaxation rates for CO(ν ⩽ 13) with CO(ν = 0), OCS, O2 and He
✍ Scribed by G. Hancock; I.W.M. Smith
- Publisher
- Elsevier Science
- Year
- 1971
- Tongue
- English
- Weight
- 412 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0009-2614
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Steady state fluorescence experiments yielded effective cross sections for the vibrational rekvmtion and quenching in collisions of electronica??y excited CO molecules, in single vibrational levels u = 0 to 8 of the A'Ei state, with rare gas atoms. Vibrational relaxation was found to proceed not onl