𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Vibrational relaxation dynamics of the X̃1∑g+ state of C3

✍ Scribed by Y. Gu; Michael L. Lesiecki; Stephen E. Bialkowski; William A. Guillory

Publisher
Elsevier Science
Year
1982
Tongue
English
Weight
526 KB
Volume
92
Category
Article
ISSN
0009-2614

No coin nor oath required. For personal study only.

✦ Synopsis

The vrbrational relaxauon dynamics of the ground '$ electronic start oiCJ has been studied iollo~rng IR mulrrple photon diiociatron of aknc. Wavelength and trmc resolved spectra, using dye laser-Induced ~luorcsccncc arc used to charactetue the vibrational levels and Iheir CorKspondfflP nse and decay rates. 'rbratronal rclaxrlion rates arc rcportcd for+ C3( ' $. 100 or 1 IO) in the presence of Ar. He, Nz. 0:. and CzHz, rn addrtron to the reactron raw constant of C~('~,.@OO) nirh CzH2 of(Z.2 f 0 10) X ICI-" cm3 molecule-' s-'.

📜 SIMILAR VOLUMES

Spectroscopy of the CH3Zn radical. Vibra
Spectroscopy of the CH3Zn radical. Vibrational frequencies and electronic configurations of the X̃, Ã, and C̃ states
✍ Robert L. Jackson 📂 Article 📅 1990 🏛 Elsevier Science 🌐 English ⚖ 636 KB

The monoalkyl zinc radical, CHJn, may be observed by laser-induced fluorescence following UV photodissociation of ( CH3)2Zn. The fluorescence spectrum obtained upon excitation of the 08 and the 2: bands of the A-2 transition was assigned. A very simple fluorescence spectrum is obtained upon excitat

Vibrational motion in the X3∑g− state of
Vibrational motion in the X3∑g− state of N3+
✍ G. Chambaud; P. Rosmus; F. Bennett; J.P. Maier; A. Spielfiedel 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 332 KB

We have generated an ab initio near-equilibrium three-dimensional potential energy function for the X3X, state of N: using highly correlated multireference configuration interaction wavefunctions. The nuclear motion problem has been solved variationally and the vibrational energy levels up to 3000 c

The vibrational population inversion and
The vibrational population inversion and relaxation kinetics of the C*2, d 3Πg state
✍ Li Xuechu; Lou Nanquan 📂 Article 📅 1980 🏛 Elsevier Science 🌐 English ⚖ 472 KB

The chemihzmrncsccnr spectra of C;, d 3rlg-~ 3ilu, PV = 0 sequence from the reaction Na + CC&J have been obtained. The C;, d 3tl,, U' = 6 level is formed preferentially. The quenchme and vlbrahonal relavatlon rates of the Ct. d 311g stite HI Ar are 1.9 X lo6 and 2.2 X IO6 Torr-' s-r, respectively. N

Characterization of the c3Σ(+) State of
Characterization of the c3Σ(+) State of SCF - The c3Σ+-X1Σ+ System
✍ E.A. Shenyavskaya; J. Verges; A. Topouzkhanian; M.A. Lebeaultdorget; J. Dincan; 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 326 KB

Thermal emission of scandium monofluoride has been spectroscopically investigated at high resolution in the region \(7000-12000 \mathrm{~cm}^{-1}\) with a Fourier transform spectrometer. The predicted low-energy \(c^{3} \Sigma^{+}\)state is observed in a transition to the ground state; six bands of