𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Vibrational motion in the X3∑g− state of N3+

✍ Scribed by G. Chambaud; P. Rosmus; F. Bennett; J.P. Maier; A. Spielfiedel

Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
332 KB
Volume
231
Category
Article
ISSN
0009-2614

No coin nor oath required. For personal study only.

✦ Synopsis

We have generated an ab initio near-equilibrium three-dimensional potential energy function for the X3X, state of N: using highly correlated multireference configuration interaction wavefunctions. The nuclear motion problem has been solved variationally and the vibrational energy levels up to 3000 cm-' are given. The antisymmetric stretch wavenumber has been calculated to be 929 cm-', and the symmetric stretch wavenumber to be 1190 cm -l, in opposite order to that calculated previously. The flat shape of the potential along the asymmetric displacement coordinate leads to strong anharmonic resonances.

📜 SIMILAR VOLUMES

Vibrational relaxation dynamics of the X
Vibrational relaxation dynamics of the X̃1∑g+ state of C3
✍ Y. Gu; Michael L. Lesiecki; Stephen E. Bialkowski; William A. Guillory 📂 Article 📅 1982 🏛 Elsevier Science 🌐 English ⚖ 526 KB

The vrbrational relaxauon dynamics of the ground '$ electronic start oiCJ has been studied iollo~rng IR mulrrple photon diiociatron of aknc. Wavelength and trmc resolved spectra, using dye laser-Induced ~luorcsccncc arc used to charactetue the vibrational levels and Iheir CorKspondfflP nse and decay

The bending vibration of n=3 states of H
The bending vibration of n=3 states of H3
✍ Wolfgang Ketterle 📂 Article 📅 1989 🏛 Elsevier Science 🌐 English ⚖ 325 KB

Bending frequencies were determined for n=3 states of H,: v,(3s\*A', ) =2587.9 cm-', v2(3d)=2517.8 cm-'. A simple model describing the 3d states of H1 with excitation of the bending mode has been developed.

Studies on the reaction N + N3 → N2(B 3Π
Studies on the reaction N + N3 → N2(B 3Πg) + N2(X 1Σ+g)
✍ K. Yamasaki; T. Fueno; O. Kajimoto 📂 Article 📅 1983 🏛 Elsevier Science 🌐 English ⚖ 445 KB

Strongly enhanced N2 fist positive emission N2(B %-+ A 3Z',) has been observed on addition of N atoms into a flowing mixture of Cl and HNJ. The dependence of the ekssion intensity on N atom concentration gave a rate constant for the reaction N + N3 -f N1(B 'fL) + N2(X Cl + HN, -+ HCI + N3 is (8.9 i