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Vibrational Excitons in CH-Stretching Fundamental and Overtone Vibrational Circular Dichroism Spectra

✍ Scribed by Roberto Gangemi; Giovanna Longhi; France Lebon; Sergio Abbate; Leo Laux


Book ID
106213503
Publisher
Springer Vienna
Year
2005
Tongue
English
Weight
311 KB
Volume
136
Category
Article
ISSN
0026-9247

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✍ Sergio Abbate; Giovanna Longhi; Claudio Santina πŸ“‚ Article πŸ“… 2000 πŸ› John Wiley and Sons 🌐 English βš– 263 KB πŸ‘ 2 views

Two theoretical models for the interpretation of the existing data of CH-stretching overtones' vibrational circular dichroism data are presented. The first model is based on the quantum mechanical Van Vleck contact transformation theory and is applied to the full vibrational problem, the second is b

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✍ Roberto Gangemi; Giovanna Longhi; Sergio Abbate πŸ“‚ Article πŸ“… 2005 πŸ› John Wiley and Sons 🌐 English βš– 179 KB πŸ‘ 1 views

## Abstract We establish the general behavior of absorption and vibrational circular dichroism spectra (VCD) of a chiral HCCH fragment lacking all symmetry elements; the study is limited to CH‐stretching modes, and the Hamiltonian employed is written in terms of normal‐mode coordinates and momenta