Vibrational Excitons in CH-Stretching Fundamental and Overtone Vibrational Circular Dichroism Spectra
β Scribed by Roberto Gangemi; Giovanna Longhi; France Lebon; Sergio Abbate; Leo Laux
- Book ID
- 106213503
- Publisher
- Springer Vienna
- Year
- 2005
- Tongue
- English
- Weight
- 311 KB
- Volume
- 136
- Category
- Article
- ISSN
- 0026-9247
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π SIMILAR VOLUMES
Two theoretical models for the interpretation of the existing data of CH-stretching overtones' vibrational circular dichroism data are presented. The first model is based on the quantum mechanical Van Vleck contact transformation theory and is applied to the full vibrational problem, the second is b
## Abstract We establish the general behavior of absorption and vibrational circular dichroism spectra (VCD) of a chiral HCCH fragment lacking all symmetry elements; the study is limited to CHβstretching modes, and the Hamiltonian employed is written in terms of normalβmode coordinates and momenta