A Comparative Study of Overtone CH-Stretching Vibrational Circular Dichroism Spectra of Fenchone and Camphor †
✍ Scribed by Longhi, Giovanna; Gangemi, Roberto; Lebon, France; Castiglioni, Ettore; Abbate, Sergio; Pultz, Vaughan M.; Lightner, David A.
- Book ID
- 120084397
- Publisher
- American Chemical Society
- Year
- 2004
- Tongue
- English
- Weight
- 346 KB
- Volume
- 108
- Category
- Article
- ISSN
- 1089-5639
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📜 SIMILAR VOLUMES
Two theoretical models for the interpretation of the existing data of CH-stretching overtones' vibrational circular dichroism data are presented. The first model is based on the quantum mechanical Van Vleck contact transformation theory and is applied to the full vibrational problem, the second is b
## Abstract We establish the general behavior of absorption and vibrational circular dichroism spectra (VCD) of a chiral HCCH fragment lacking all symmetry elements; the study is limited to CH‐stretching modes, and the Hamiltonian employed is written in terms of normal‐mode coordinates and momenta