The vibration-vibration ene=y transfer of HCI gas initially excited to the tirst vibrational level is measured by monitoring the fluorescence of the 2-1 transition. The rate constant for the process is found to be 0.9 x IO5 secwl tom-'.
Vibrational energy transfer in HCl–CO mixtures
✍ Scribed by Seery, Daniel J.
- Book ID
- 125520310
- Publisher
- American Institute of Physics
- Year
- 1975
- Tongue
- English
- Weight
- 535 KB
- Volume
- 63
- Category
- Article
- ISSN
- 0021-9606
- DOI
- 10.1063/1.431738
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📜 SIMILAR VOLUMES
The vibrational relaxation of HCI in liquid xenon at -68°C has been studied. Vibrationally excited HCI is created following UV photolysis of HCI. The rate of relaxation of HCl as a function of HCl mole fraction in liquid xenon is the same as the correspondingrate forgas phaseHCIat -68°C. Similarly t
Vibrational relaxation of HCI( v= 1) has been studied in mixtures with Kr and Xe at room temperature with the help of laserinduced fluorescence. Relaxation rate constants of k,,( Kr) =0.3 + 0.2 and k,,( Xe) = I. I f 0.3 Torr-' s-' have been found. The increase in the relaxation efftciency of xenon c