Vibrational Energy Relaxation Rates of H 2 and D 2 in Liquid Argon via the Linearized Semiclassical Method
β Scribed by Navrotskaya, Irina; Geva, Eitan
- Book ID
- 126271222
- Publisher
- American Chemical Society
- Year
- 2007
- Tongue
- English
- Weight
- 99 KB
- Volume
- 111
- Category
- Article
- ISSN
- 1089-5639
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π SIMILAR VOLUMES
Rate constants for the vibrational deactivation of 12C'60( u= 1) by Hz and D1 have been measured in liquid D2 solution over the temperature range 25 to 35 K. The '2C'60 was vibrationally excited using a frequency-doubled CO2 laser and the resulting infrared fluorescence was analysed to yield the rat
The cone or acceptance for H+H= reactive collisions is shown Lo open up upon strelching of the H, bond. AL a given wtmslational energy, the sreric faclor is thus much larger for vibrzkonally cxcircd rcngems as demonswatcd by class&l IrajccLoq compulorions for H+ D?(U) and D+Hz(o). AI a given lolaI c