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Vibrational Energy Relaxation Rates of H 2 and D 2 in Liquid Argon via the Linearized Semiclassical Method

✍ Scribed by Navrotskaya, Irina; Geva, Eitan


Book ID
126271222
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
99 KB
Volume
111
Category
Article
ISSN
1089-5639

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πŸ“œ SIMILAR VOLUMES


The vibrational deactivation of 12C16O b
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Rate constants for the vibrational deactivation of 12C'60( u= 1) by Hz and D1 have been measured in liquid D2 solution over the temperature range 25 to 35 K. The '2C'60 was vibrationally excited using a frequency-doubled CO2 laser and the resulting infrared fluorescence was analysed to yield the rat

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The cone or acceptance for H+H= reactive collisions is shown Lo open up upon strelching of the H, bond. AL a given wtmslational energy, the sreric faclor is thus much larger for vibrzkonally cxcircd rcngems as demonswatcd by class&l IrajccLoq compulorions for H+ D?(U) and D+Hz(o). AI a given lolaI c