Preliminary results arc reported of a Monte Carlo trajectory study of intramolecular vibrational ener\_w relaxation in a model of benzene. Very little relaxation 1s found to occur on d picosecond timeswle. The rate of intramolecular wbrational energy relaxation appears to be dependent upon the natur
Vibrational energy relaxation processes in heme proteins
β Scribed by L. Genberg; F. Heisel; G. McLendon; R.J. Dwayne Miller
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- English
- Weight
- 565 KB
- Volume
- 40-41
- Category
- Article
- ISSN
- 0022-2313
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Opto-acoustic techmques have been used to measure vibrational energy relaxation tn methyl halides and their mixtures wth tnert gases Under certain condihons tune-resolved measurements gwe direct evidence of a V-R-T relaxation channel parallel to the V-T relaxation channel Comparison with infrared fl
Subsequenttoe\cmn\_e1.~ b>--nCO 1 laser pulse,U~oiesccnceh~beenderccted,rom 1v3 ofCHpF trappedm raregas mxrlces. Zu3 IS acavated by V-V energy transfer and deactivates at twce the rate of YJ rehntlon X kmetlc model IS presented to interpret these observations
The O-H fundamental band profiles of several alcohols in various solvents have been studied by the correlation function technique. It was found that the rotational contribution to the O-H band shape is not significant for these molecules except for methanol. The denendence of the vibrational correla