The kinetics of vibrational energy transfer and relaxation processes in matrix isolated CH3F
โ Scribed by V.A. Apkarian; Eric Weitz
- Publisher
- Elsevier Science
- Year
- 1980
- Tongue
- English
- Weight
- 580 KB
- Volume
- 76
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
Subsequenttoe\cmn_e1.~ b>--nCO 1 laser pulse,U~oiesccnceh~beenderccted,rom 1v3 ofCHpF trappedm raregas mxrlces. Zu3 IS acavated by V-V energy transfer and deactivates at twce the rate of YJ rehntlon X kmetlc model IS presented to interpret these observations
๐ SIMILAR VOLUMES
Infrared double resonance and saturation techniques have both been used to measure the V-T relaxation of the 19 mode of CH3F in dilute solution in the cryogenic liquid hosts 02 and Ar. With the former technique, a relaxation time of 375 + 35 ns is found in liquid 02 while in liquid Ar the relaxation
The purpose of this paper is to study the conditions under which the rate constat exhiiits the Arrhenius type of temperature dependence and the damping effect on the rate constant. According tc the starvation kinetics, the rate of reaction is determined by the rate of enew flow in the high temperatu
The kinetics of the gas-phase reaction of CH3F with 12 have been studied spectrophotometrically from 629 to 710 K, and were determined to be consistent with the following mechanism: (KIJ squares analysis of the kinetic data taken in the initial stages of reaction resulted in log k4 (M-w) = (11.3 f