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The kinetics of vibrational energy transfer and relaxation processes in matrix isolated CH3F

โœ Scribed by V.A. Apkarian; Eric Weitz


Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
580 KB
Volume
76
Category
Article
ISSN
0009-2614

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โœฆ Synopsis


Subsequenttoe\cmn_e1.~ b>--nCO 1 laser pulse,U~oiesccnceh~beenderccted,rom 1v3 ofCHpF trappedm raregas mxrlces. Zu3 IS acavated by V-V energy transfer and deactivates at twce the rate of YJ rehntlon X kmetlc model IS presented to interpret these observations


๐Ÿ“œ SIMILAR VOLUMES


Vibrational energy relaxation of CH3F di
โœ S.R.J. Brueck; T.F. Deutsch; R.M. Osgood Jr. ๐Ÿ“‚ Article ๐Ÿ“… 1977 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 553 KB

Infrared double resonance and saturation techniques have both been used to measure the V-T relaxation of the 19 mode of CH3F in dilute solution in the cryogenic liquid hosts 02 and Ar. With the former technique, a relaxation time of 375 + 35 ns is found in liquid 02 while in liquid Ar the relaxation

Temperature dependence of rate constants
โœ S.M. Ma; H. Eyring; S.H. Lin; Dale Wutz; Y. Fujimura ๐Ÿ“‚ Article ๐Ÿ“… 1978 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 332 KB

The purpose of this paper is to study the conditions under which the rate constat exhiiits the Arrhenius type of temperature dependence and the damping effect on the rate constant. According tc the starvation kinetics, the rate of reaction is determined by the rate of enew flow in the high temperatu

Kinetics of the gas-phase reaction CH3F
โœ J. M. Pickard; A. S. Rodgers ๐Ÿ“‚ Article ๐Ÿ“… 1983 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 374 KB

The kinetics of the gas-phase reaction of CH3F with 12 have been studied spectrophotometrically from 629 to 710 K, and were determined to be consistent with the following mechanism: (KIJ squares analysis of the kinetic data taken in the initial stages of reaction resulted in log k4 (M-w) = (11.3 f