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Temperature dependence of rate constants of thermal activated processes and vibrational relaxation in starvation kinetics

✍ Scribed by S.M. Ma; H. Eyring; S.H. Lin; Dale Wutz; Y. Fujimura


Publisher
Elsevier Science
Year
1978
Tongue
English
Weight
332 KB
Volume
58
Category
Article
ISSN
0009-2614

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✦ Synopsis


The purpose of this paper is to study the conditions under which the rate constat exhiiits the Arrhenius type of temperature dependence and the damping effect on the rate constant. According tc the starvation kinetics, the rate of reaction is determined by the rate of enew flow in the high temperature range. We shall show that the rate of ener_ey flow (vibrational relaxation) reaches a finite limit in the high temperature condition.