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Vibrational energy exchange of the DF (ν=2) state with DF (ν=0)

✍ Scribed by Jerry F. Bott

Publisher
Elsevier Science
Year
1973
Tongue
English
Weight
312 KB
Volume
23
Category
Article
ISSN
0009-2614

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✦ Synopsis

IIhe energy transfer rate for the reaction DF (U = 1) + DF (u = 1) 'y DF(v=O)-+DF(u=2)+aE=91.6cm-' has been studied in a combined shock-tube laser-induced fluorescence experiment at temperatures from 295 to 720 0 K. The rate coefficient k,, for the exothermic reaction was found to vary as T' .when expressed in units of cm3/mole set At T= 295°K. the probability of the reaction is approximately 0.2 per collision.

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