Raman spectra are reported for the v1 bands of germane and germane-d,. Fourier transformation of the band shapes provided vibrational autocorrelation functions. These functions were modeled by a memory-function procedure. Evidence for resonant vibrational energy transfer and higher order cumulant-ex
Vibrational Dephasing of PHD2 in liquid and solid PD3
โ Scribed by Richard E. Wilde
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- English
- Weight
- 205 KB
- Volume
- 67
- Category
- Article
- ISSN
- 0009-2614
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A model for (indirect) dephasing of a high-frequency vibrational mode caused by intramolecular anharmonic coupling to a low-frequency vibration is proposed which is an extension of the exchange model of Anderson and Kubo. It contains apart of the frequency shift of the combination band and the lifet
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