On the assumption that the stretching exponent value in the stretched exponential model is the same for both and vibrations of SCN-, an "additionalΓ broadening of the line has been identiΓed and attributed m 1 (R') m 3 (R') m 1 to dissipative losses due to ion-dipole interactions between cations and
Vibrational dephasing in aqueous KSCN solution. A memory function and stretched exponential study
β Scribed by Qiao Feng; Richard E. Wilde
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- English
- Weight
- 454 KB
- Volume
- 150
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
β¦ Synopsis
Raman spectra of 5.0 and 8.4 M aqueous K!XN solutions were recorded. The spectra were analyzed by memory-function and stretched-exponential modeling procedures. The two procedures modeled the vibrational autocorrelation functions within experimental error. The success of the stretched exponential model was found to be its very good tit to the memory functions.
π SIMILAR VOLUMES
Ultrasonic velocities and densities of aqueous solutions of cetyltrimethylammonium chloride have been measured at concentrations below \(0.35 \mathrm{~mol}^{-1}\) at 25,35 , and \(45^{\circ} \mathrm{C}\). Apparent molar volume and apparent molar adiabatic compressibility properties of the aqueous su