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Vibrational branching ratios and photoionization dynamics for N2O

✍ Scribed by E.D. Poliakoff; Ming-Hang Ho; M.G. White; G.E. Leroi


Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
552 KB
Volume
130
Category
Article
ISSN
0009-2614

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✦ Synopsis


Vibrational resolved constant-ionic-state spectroscopy is used to study photoionization of N20. We determine the ratio of partial photoionization cross sections for alternative vibrational levels ofthe NrO+ (A 'Z + ) state and these vibrational branching ratios are dependent on excitation energy, implying that there is a breakdown of the Franck-Condon approximation. These results may be sampling the wings of a shape resonance.


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