Emission spectra of the N20c (A %+-R "II,) system produced by electron impact on jet-cooled N20 have been measured at impact energies of 18-300 eV. The vibrational population for the I' level relative to the 0' level of the A state was found to decrease rapidly with increasing impact energy and leve
Vibrational branching ratios and photoionization dynamics for N2O
β Scribed by E.D. Poliakoff; Ming-Hang Ho; M.G. White; G.E. Leroi
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- English
- Weight
- 552 KB
- Volume
- 130
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
Vibrational resolved constant-ionic-state spectroscopy is used to study photoionization of N20. We determine the ratio of partial photoionization cross sections for alternative vibrational levels ofthe NrO+ (A 'Z + ) state and these vibrational branching ratios are dependent on excitation energy, implying that there is a breakdown of the Franck-Condon approximation. These results may be sampling the wings of a shape resonance.
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Photoemission cmss sections of Penning ionization have been measured at 150 meV for collision of He\*( 2 %3 ) with N1O by using the crossed-beam method and observing fluorescence in the 335-415 nm region. The emission cross section of the NzO+ (;d %+-g %) system obtained is (7.7 f 2.1) x 10-\*0m2. T
The photoelectron branching ratio for the production of the (2at))' state of H20+ has been measured in the 50-200 eV photon-energy range usmg synchrotron radiation and magic-angle photoelectron spectroscopy. Partial photoionization cross sections are derived from the measured branching ratios using
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