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Vibrational assignments from sharp line luminescence of a higher excited state of ReCl62− in cubic host crystals

✍ Scribed by Hans-Herbert Schmidtke; Rainer Wernicke

Publisher: Elsevier Science
Year: 1976
Tongue: English
Weight: 329 KB
Volume: 40
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(76)85092-0

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✦ Synopsis

The micro crystalline hnninescence spectrum of [ ReC& 1 2doped in !&[SnC16] and Kz[PtC&] due to the i' ,(*T+ t&) + rs("Aza, t&j transition has been measured at liquid nitrogen temperature. The bands are assigned to internal complex and lattice vibrational modes using also fu IR and Raman data. A pair of bands located at zero phonon position and a couple of satellite bands near fundamental peaks indicate that the electronic gound state is split into two Kramers doublets by about 10 cm-' due to 3 second order Jihn-Teller distortion.

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The micro crystalIine luminescence spectrum of @&-doped in K2PtC16 originating from rl('Alg)+ rX3TIg), i = 1 3 4 5 , , I , electronic transitions has been measured at 10 K. The bands are assigned to internal complex and lattice viira- tional modes u.sbg experimental data (FIR and Raman) and theoreti