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Vibrational assignment of sharp line luminescence bands from a higher excited state of OsCl2−6 doped in K2PtCl6

✍ Scribed by Rainer Wernicke; Gerd Eyring; Hans-Herbert Schmidtke

Publisher: Elsevier Science
Year: 1978
Tongue: English
Weight: 396 KB
Volume: 58
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(78)80291-7

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✦ Synopsis

The micro crystalIine luminescence spectrum of @&-doped in K2PtC16 originating from rl('Alg)+ rX3TIg), i = 1 3 4 5 , , I , electronic transitions has been measured at 10 K. The bands are assigned to internal complex and lattice viira- tional modes u.sbg experimental data (FIR and Raman) and theoretical results (dispersion curves). The only zero-phonon band observed is due to the group theoretical allowed rI(lAlg) -+ I+_+(~T~~) transition.

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