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Versatile and convenient routes to functionalized poly(ferrocenylsilanes)

✍ Scribed by Frieder Jäkle; Zhuo Wang; Ian Manners

Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
81 KB
Volume
21
Category
Article
ISSN
1022-1336

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## Abstract A novel and convenient route to the first poly(ferrocenylsilanes) with alkoxy, aryloxy, and amino substituents at silicon is reported. The reaction sequence involves (i) unexpectedly facile and clean halogen replacement at the bridging atom of a readily accessible dichlorosilyl‐bridged

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## Abstract **Summary:** The synthesis of a series of polyferrocenylsilanes (PFSs) containing CC functionalities in the side‐group structure and their subsequent derivatization by hydrosilylation chemistry are described. Hydrosilylation is shown to be an effective postpolymerization functionalizat

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Novel poly(silylenemethylenes) have been prepared by the ring-opening polymerization of 1,3-disilacyclobutanes followed by a protodesilylation reaction with triflic acid. The silicon-aryl bond cleavage could be controlled by using different leaving groups, for instance phenyl-and para-anisyl substit