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A Versatile and Efficient Hydrosilylation Route to Functionalized Polyferrocenylsilanes

✍ Scribed by Stefan Hilf; Paul W. Cyr; David A. Rider; Ian Manners; Tamao Ishida; Yoshiki Chujo

Publisher: John Wiley and Sons
Year: 2005
Tongue: English
Weight: 116 KB
Volume: 26
Category: Article
ISSN: 1022-1336
DOI: 10.1002/marc.200500160

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✦ Synopsis

Abstract

Summary: The synthesis of a series of polyferrocenylsilanes (PFSs) containing CC functionalities in the side‐group structure and their subsequent derivatization by hydrosilylation chemistry are described. Hydrosilylation is shown to be an effective postpolymerization functionalization method, particularly in the case of poly(ferrocenylmethylvinylsilane), which can be prepared by photolytic anionic ring‐opening polymerization of the corresponding ferrocenophane monomer.
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