**Iridoids from __Verbascum nigrum__ L.** Two new iridoid glycosides, nigroside 1 ( 6‐__O__‐(3‐__O__‐einnamoyl‐α‐L‐rhamno‐pyranosyl)aucubin **(2)**, and nigroside 2 (6‐__O__‐(2‐__O__‐cinnamoyl‐α‐L‐rhamnopy‐ranosyl)aucubin **(3)**, and the known compound laterioside **(1)** have been isolated fro
Verbascenin, ein macrocyclisches Spermin-Alkaloid aus verbascum 184. Mitteilung über organische Naturstoffe
✍ Scribed by Karlheinz Seifert; Siegfried Johne; Manfred Hesse
- Publisher
- John Wiley and Sons
- Year
- 1982
- Tongue
- German
- Weight
- 472 KB
- Volume
- 65
- Category
- Article
- ISSN
- 0018-019X
No coin nor oath required. For personal study only.
✦ Synopsis
Verbascenine, a Macrocyclic Spermine Alkaloid Isolated from Verbascum
The new spermine alkaloid verbascenine (1) has been isolated from extracts of the aerial parts of Verbascum phoeniceum L. and V nigrum L. The structure of the alkaloid was elucidated by chemical degradation and by a study of the spectral properties of the alkaloid and its derivatives. Compared to the 13‐membered alter native 7 the 17‐membered structure 1 is preferred on the basis of mass spectral arguments.
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## Abstract Another representative of this group of alkaloids, aristoteline (**2**), was also isolated from __A. peduncularis__. This natural compound has previously been isolated from __A. serrata__ and __A. chilensis__.
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