Variation of the polarizability of the hydrogen molecule ion and the hydrogen molecule with internuclear separation

✍ Scribed by Daniel Zeroka

• Publisher: John Wiley and Sons
• Year: 1974
• Tongue: English
• Weight: 212 KB
• Volume: 8
• Category: Article
• ISSN: 0020-7608
• DOI: 10.1002/qua.560080110

✦ Synopsis

Abstract

The variation of the polarizability of H and H~2~ with internuclear separation R = 1.6 – R = 2.4 a.u. for H and R = 1.0 – R = 2.0 a.u. for H~2~ is determined using a variational method suggested by Das and Bersohn. From these data, values of 〈α〉~0,J~ for which nuclear motion due to zero point vibration and centrifugal stretching is taken into account, are calculated at 300°K. The relative percent increases of the motion averaged values compared to the equilibrium values are as follows: 10.50% for H and 6.52% for H~2~.