Depasse and J.M. Vigoureux, The use of the stationary perturbation method in calculations of surface-induced dynamic polarizability, Chem. Phys. Letters 160 (1989) 311.
A variation-perturbation calculation of the dynamic polarizability of the H2 molecule
β Scribed by J. Rychlewski
- Publisher
- Elsevier Science
- Year
- 1980
- Tongue
- English
- Weight
- 243 KB
- Volume
- 73
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
A varMlon-perturbation method has been used to calculate the dynamic polarizabllities al(w) and Q,,(W) of the hydrogen molecule. Values have been obtained for frequencies below the first exatation for a fned bond len@h of I.4 au.
π SIMILAR VOLUMES
We present a complete calculation of the dynamical polarizability induced on an atom or a centrosymmetric molecule by the presence of a perfect metallic surface. This polarizability, which appears as a direct consequence of modifications by the surface of vacuum fluctuations is here calculated by us
We use a recently proposed method to calculate the electric ~olarizabilities of the hydrogen molecule and the hydrogen molecular ion We solve the first-order and second+xder perturbation equations by variational procedures and we use the solution of the second-order perturbation equation to improve
The parallel and perpendicular dipole polarizabilities of HZ+ are calculated for various icternuclear distances by a numerical single-centre procedure. \* This research was supported by the Advanced Research Projects Agency of the Department of Defense and was monitored by the Office of Naval Resear