An investigation of the influence of angular strain on the stretching vibration of carbonyl groups fa cyclic ketones is made. The results obtsined by a normal coordinate treatment show that frequency variation is due both to kinetic energy and potential energy effects.
Variation of the carbonyl characteristic frequency in cyclic ketones
β Scribed by B. Galabov; S. Suzuki; W.J. Orville-Thomas
- Publisher
- Elsevier Science
- Year
- 1980
- Tongue
- English
- Weight
- 284 KB
- Volume
- 73
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
β¦ Synopsis
An analysts based on changes m the v(C=O) frequencies m four cycloalkanoncs
shows that kmemattc and potentirrl energy etfects are Important m ail cases As the rmg srze mcreases so does the relauve importance of the potentiial energy effect as compared w&h the kmemattc eftect.
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