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Reactions of the Carbonyl Group in Fluorinated Ketones

✍ Scribed by Dr. N. P. Gambaryan; E. M. Rokhlin; Yu. V. Zeifman; Chen Ching-yun; Prof. I. L. Knunyants

Publisher
John Wiley and Sons
Year
1966
Tongue
English
Weight
877 KB
Volume
5
Category
Article
ISSN
0044-8249

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✦ Synopsis

Thechemistry ofpolyfluorinatedketones has recently received a great dealof attention [1 I 21 La]. The carboriyl and imino groups of the fluorinated ketones and their imines react in many different ways. Zn particular, the electron-attracting perfluoroalkyl groups intensify the elecrrophilic properties and weaken the nucleophilic properties of the carbonyl group. The perfluoroalkyl group also hinders the heterolytic removal of the hydroxyl group from adducts c by reducing the stability of the carbonium ion cx. The increased electrophilicity of the carbonylgroup and the increased stability of the addition prod-

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