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Variable transition-state structure in the solvolyses of substituted benzyl p-toluenesulfonates

✍ Scribed by Kevill, Dennis N.; Ren, Haobo


Book ID
126124295
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
270 KB
Volume
54
Category
Article
ISSN
0022-3263

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## Abstract A comparison of the solvolysis rates of the substituted 2‐__exo__‐ and 2‐__endo__ ‐norbornyl __p__‐toluenesulfonates **1, 2, 3** and **4** and the substituted 1‐ and 2‐adamantyl sulfonates **9** and **10**, respectively, in 80% ethanol and 97% trifluoroethanol has shown that the sensiti