𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Norbornanes. Part 18. Inductive Charge Dispersal in the Solvolyses of 4- and 5-Substituted 2-Norbornyl p-Toluenesulfonates

✍ Scribed by Francesco Fuso; Cyril A. Grob; Pawel Sawlewicz; Guo Wei Yao

Publisher
John Wiley and Sons
Year
1986
Tongue
German
Weight
435 KB
Volume
69
Category
Article
ISSN
0018-019X

No coin nor oath required. For personal study only.

✦ Synopsis

As measured by the pK, of 4-substituted quinuclidines [3] For the influence of 6-endo-substituents, see [2].

Derived from the equation log k = p,uy + log k,.

📜 SIMILAR VOLUMES

Solvent Dependence of Inductivity in the
Solvent Dependence of Inductivity in the Solvolyses of Substituted Norbornyl p-Toluenesulfonates. Norbornanes, Part 14
✍ Rolf Bielmann; Marcus Christen; Peter Flury; Cyril A. Grob 📂 Article 📅 1983 🏛 John Wiley and Sons 🌐 German ⚖ 436 KB

## Abstract A comparison of the solvolysis rates of the substituted 2‐__exo__‐ and 2‐__endo__ ‐norbornyl __p__‐toluenesulfonates **1, 2, 3** and **4** and the substituted 1‐ and 2‐adamantyl sulfonates **9** and **10**, respectively, in 80% ethanol and 97% trifluoroethanol has shown that the sensiti

Carbon Participation in the Solvolysis o
Carbon Participation in the Solvolysis of 6- and 7-Substituted 2-Norbornyl p-Toluenesulfonates. Norbornanes, Part 11
✍ Peter Flury; Cyril A. Grob 📂 Article 📅 1983 🏛 John Wiley and Sons 🌐 German ⚖ 473 KB 👁 1 views

## Abstract The solvolysis rates and products of several 7‐__anti__‐substituted 2‐__endo__‐norbornyl __p__‐toluenesulfonates **11** have been determined and compared with those of the previously reported 6‐__exo__‐substituted 2‐__exo__‐norbornyl __p__‐toluenesulfonates **1.** Although the number of

Carbon Participation in the Solvolysis o
Carbon Participation in the Solvolysis of 6-endo-Substituted 2-exo-Norbornyl Toluenesulfonates. Norbornanes part 6
✍ Cyril A. Grob; Bettina Günther; Reinhard Hanreich 📂 Article 📅 1981 🏛 John Wiley and Sons 🌐 German ⚖ 471 KB 👁 1 views

## Abstract The solvolysis rate constants __k__ for the 6‐__endo__‐substituted 2‐__exo__‐norbornyl toluenesulfonates **7** have been determined. Values of log__k__ correlate well with the respective inductive constants of the substitutents except when the latter are nucleophilic and therefore lead

Polar versus steric effects in the solvo
Polar versus steric effects in the solvolysis of 6endo-substituted 2endo-norbornyl p-toluenesulfonates. Norbornanes, Part 8
✍ Cyril A. Grob; Bettina Günther; Reinhard Hanreich 📂 Article 📅 1982 🏛 John Wiley and Sons 🌐 German ⚖ 337 KB 👁 1 views

## Abstract The solvolysis rates and products of the 6__endo__‐R‐substituted 2__endo__‐norbornyl toluenesulfonates **6a**–**6i** have been determined. The rates of **6a**–**6g** correlate with the inductive constants σ the 6__endo__‐substituents and are not related to the size of the latter. It is

Carbon Participation in the Solvolysis o
Carbon Participation in the Solvolysis of Tertiary Norbornyl Derivatives Norbornanes. Part 15. 6-substituted 2-methylnorbornyl 2-exo- and 2-endo-2,4-dinitrophenyl ethers
✍ Cyril A. Grob; Adrian Waldner 📂 Article 📅 1983 🏛 John Wiley and Sons 🌐 German ⚖ 352 KB 👁 1 views

The solvolysis rates and products of the tertiary 2-methyl-2-exo-and -2-endonorbornyl 2,4-dinitrophenyl ethers 1 and 2, (X = 2,4-(NO,),C,H,O) have been determined. The different sensitivities of the rates of these ethers to the inductive effect of substituents at C(6) indicate that graded bridging o