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Variable Synthesis of Alcohols and Ketones Using the Grignard Method as a Form of MPVO Reaction.

✍ Scribed by Michael Schroeter


Publisher
John Wiley and Sons
Year
2005
Weight
19 KB
Volume
36
Category
Article
ISSN
0931-7597

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The Mg-Oppenauer Oxidation as a Mild Met
✍ Ralf J. Kloetzing; Arkady Krasovskiy; Paul Knochel πŸ“‚ Article πŸ“… 2006 πŸ› John Wiley and Sons 🌐 English βš– 246 KB πŸ‘ 1 views

## Abstract Magnesium alkoxides undergo a hydride‐transfer oxidation with benzaldehyde as the oxidant. This magnesium variant of the Oppenauer oxidation was used for the synthesis of polyfunctional biaryl ketones. LiCl was found to promote this reaction by enhancing the solubility of magnesium alko