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The Mg-Oppenauer Oxidation as a Mild Method for the Synthesis of Aryl and Metallocenyl Ketones.

✍ Scribed by Ralf J. Kloetzing; Arkady Krasovskiy; Paul Knochel


Publisher
John Wiley and Sons
Year
2007
Weight
43 KB
Volume
38
Category
Article
ISSN
0931-7597

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The Mg-Oppenauer Oxidation as a Mild Met
✍ Ralf J. Kloetzing; Arkady Krasovskiy; Paul Knochel πŸ“‚ Article πŸ“… 2006 πŸ› John Wiley and Sons 🌐 English βš– 246 KB πŸ‘ 2 views

## Abstract Magnesium alkoxides undergo a hydride‐transfer oxidation with benzaldehyde as the oxidant. This magnesium variant of the Oppenauer oxidation was used for the synthesis of polyfunctional biaryl ketones. LiCl was found to promote this reaction by enhancing the solubility of magnesium alko