Solubilities of sodium peroxydisulfate and potassium peroxydisulfate in water and vapour pressures of saturated solutions were determined as a function of temperature. The vapour pressures served to evaluate the water activities, osmotic coefficients and molar enthalpies of vaporization. The molar e
Vapour pressure measurements and thermodynamic properties of aqueous solutions of sodium acetate
โ Scribed by Roland Beyer; Michael Steiger
- Publisher
- Elsevier Science
- Year
- 2002
- Tongue
- English
- Weight
- 173 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0021-9614
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โฆ Synopsis
The vapour pressure of (sodium acetate + water) was measured in the temperature range 278.15 K to 308.15 K and in the molality range 0.65 mol โข kg -1 to 6.47 mol โข kg -1 with a static method. Water activities and osmotic coefficients were calculated. A comprehensive search of the available literature for the relevant thermodynamic data of the investigated system was carried out. The most reliable values were used in a least-squares treatment using the Pitzer formalism in the temperature range 255 K to 398 K and the molality range 0 mol โข kg -1 to 25 mol โข kg -1 .
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