Vapor-Liquid equilibria for five cryogenic mixtures

✍ Scribed by F. B. Sprow; J. M. Prausnitz

• Publisher: American Institute of Chemical Engineers
• Year: 1966
• Tongue: English
• Weight: 477 KB
• Volume: 12
• Category: Article
• ISSN: 0001-1541
• DOI: 10.1002/aic.690120427

✦ Synopsis

Phase equilibrium data have been obtained for the binary systems nitrogen-argon and nitrogen-carbon monoxide at 8332°K. and for the systems nitrogen-methone, argon-methane, and carbon monoxide-methane at 90.67"K. Total pressures and compositions of both phases were measured. Parameters have been calculated for the Redlich-Kister and Wilson equations for the excess Gibbs energies of the mixtures. The data are thermodynamically consistent within experimental error. NOTATION A1, Az, A3 = constants for Redlich-Kister equation B = second virial coefficient Vol. 12, No. 3 A.1.Ch.E.