The oxidation kinetics of malic acid by vanadium(V) in aqueous sulphuric acid was investigated at 303 K by monitoring the appearance of vanadium(1V) at 760 nm. The reaction showed first-order behavior with respect to vanadium(V), malic acid, and hydrogen ion concentration, respectively, regardless o
Vanadium(V) catalysis of perborate oxidation of substituted 5-oxo acids: a kinetic and mechanistic study
β Scribed by Shree Devi, S.; Muthukumaran, B.; Krishnamoorthy, P.
- Book ID
- 125372873
- Publisher
- Springer-Verlag
- Year
- 2014
- Tongue
- English
- Weight
- 563 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0947-7047
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## Abstract The oxidation of glycolic, lactic, malic, and a few substituted mandelic acids by tetraethylammonium chlorochromate (TEACC) in dimethylsulfoxide leads to the formation of corresponding oxoacids. The reaction is first order each in TEACC and hydroxy acids. Reaction is failed to induce th
A detailed kinetic study of the Mn(1I)-catalyzed and -uncatalyzed oxidation of pinacol by bromate has been carried out in aqueous acetic acid media containing Hg(I1) ions. The uncatalyzed reaction exhibits 1.5 order that is, 0.5 order in [pinacol] and 1.0 in [bromate]. A decrease in k 1 by increasin