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Vanadium-Catalyzed Asymmetric Oxidation of α-Hydroxy Esters Using Molecular Oxygen as Stoichiometric Oxidant.

✍ Scribed by Alexander T. Radosevich; Christine Musich; F. Dean Toste


Publisher
John Wiley and Sons
Year
2005
Weight
38 KB
Volume
36
Category
Article
ISSN
0931-7597

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Chiral Cobalt-Catalyzed Enantiomer-Diffe
✍ Santosh Kumar Alamsetti; Pandi Muthupandi; Govindasamy Sekar 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 196 KB

## Abstract **An efficient enantioselective** oxidative reaction catalyzed by a chiral cobalt complex has been developed by using molecular oxygen as the stoichiometric oxidant (see scheme). The very mild reaction conditions of the catalytic system provide access to a wide range of benzoins (α‐hydr