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ChemInform Abstract: Chiral Cobalt-Catalyzed Enantiomer-Differentiating Oxidation of Racemic Benzoins by Using Molecular Oxygen as Stoichiometric Oxidant.

✍ Scribed by Santosh Kumar Alamsetti; Pandi Muthupandi; Govindasamy Sekar


Publisher
John Wiley and Sons
Year
2009
Weight
30 KB
Volume
40
Category
Article
ISSN
0931-7597

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Chiral Cobalt-Catalyzed Enantiomer-Diffe
✍ Santosh Kumarβ€…Alamsetti; Pandi Muthupandi; Govindasamy Sekar πŸ“‚ Article πŸ“… 2009 πŸ› John Wiley and Sons 🌐 English βš– 196 KB

## Abstract **An efficient enantioselective** oxidative reaction catalyzed by a chiral cobalt complex has been developed by using molecular oxygen as the stoichiometric oxidant (see scheme). The very mild reaction conditions of the catalytic system provide access to a wide range of benzoins (α‐hydr