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Vanadium bromoperoxidase: Enzyme and biomimetic investigations

✍ Scribed by Alison Butler; M.J. Clague; G.E. Meister; R.A. Tschirret-Guth; J.V. Walker

Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
64 KB
Volume
59
Category
Article
ISSN
0162-0134

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## Abstract Here we report a direct observation, by electrospray ionization mass spectrometry, of the intermediate [VO(OH~2~)(OH)(OBr)]^+^, which may be involved in the catalytic cycle of the V‐HalPO enzymes. Ab initio calculations also support the stability of such a species. (Β© Wiley‐VCH Verlag G