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Structure and function of vanadium bromoperoxidases.

✍ Scribed by R. Wever; M.G.M. Tromp

Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
110 KB
Volume
43
Category
Article
ISSN
0162-0134

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## Abstract Here we report a direct observation, by electrospray ionization mass spectrometry, of the intermediate [VO(OH~2~)(OH)(OBr)]^+^, which may be involved in the catalytic cycle of the V‐HalPO enzymes. Ab initio calculations also support the stability of such a species. (Β© Wiley‐VCH Verlag G