Vanadium 7,7,8,8-Tetracyano- p -quinodimethane (V[TCNQ] 2 )-Based Magnets
β Scribed by Vickers, Elaine B.; Selby, Trent D.; Thorum, Matthew S.; Taliaferro, Michelle L.; Miller, Joel S.
- Book ID
- 127175733
- Publisher
- American Chemical Society
- Year
- 2004
- Tongue
- English
- Weight
- 182 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0020-1669
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π SIMILAR VOLUMES
The linear coupling constants desLrlbing the interaction of the one-electron molecular orbitals with the molecular vlbrations in TCNQ are caiculatcd using a semiempirlcal spectroscopically parametcrtzcd CNDO molecular orbital model. The cartcsian displacements for the normal mode of vibrations are c
A new series of cation-TCNQ salts is described: phosphiniminium cations ( 1) and ( 2) form 1:2 salts with TCNQ that are organic conductors (art 0.05-0.15 S cm-l) whereas cations ( 3) and ( 4) form insulating 1:l salts;