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Vanadium 7,7,8,8-Tetracyano- p -quinodimethane (V[TCNQ] 2 )-Based Magnets

✍ Scribed by Vickers, Elaine B.; Selby, Trent D.; Thorum, Matthew S.; Taliaferro, Michelle L.; Miller, Joel S.


Book ID
127175733
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
182 KB
Volume
43
Category
Article
ISSN
0020-1669

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The linear coupling constants desLrlbing the interaction of the one-electron molecular orbitals with the molecular vlbrations in TCNQ are caiculatcd using a semiempirlcal spectroscopically parametcrtzcd CNDO molecular orbital model. The cartcsian displacements for the normal mode of vibrations are c

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A new series of cation-TCNQ salts is described: phosphiniminium cations ( 1) and ( 2) form 1:2 salts with TCNQ that are organic conductors (art 0.05-0.15 S cm-l) whereas cations ( 3) and ( 4) form insulating 1:l salts;