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Conducting and insulating salts of phosphiniminium cations with 7,7,8,8-tetracyano-p-quinodimethane (TCNQ)

✍ Scribed by Martin R. Bryce; Adrian J. Moore; Y.H. Kim; Z-X. Liu; M.J. Nowak

Publisher: Elsevier Science
Year: 1987
Tongue: French
Weight: 177 KB
Volume: 28
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)96540-7

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✦ Synopsis

A new series of cation-TCNQ salts is described: phosphiniminium cations ( 1) and ( 2) form 1:2 salts with TCNQ that are organic conductors (art 0.05-0.15 S cm-l) whereas cations ( 3) and ( 4) form insulating 1:l salts;

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