We describe an approach to van der Waals one-fluid theory based on thermodynamic consistency and propose a method for generalising it to non-conformal fluids.
โฆ LIBER โฆ
Van der Waals-Maxwell theory, Lebowitz-Penrose limit and superstable interactions
โ Scribed by A. Gerardi; C. Marchioro; E. Olivieri; E. Presutti
- Publisher
- Springer
- Year
- 1973
- Tongue
- English
- Weight
- 560 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0010-3616
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๐ 2 views
On the basis of the adiabatic connection formula we propose several approximations for the total correlation energy functional, which, in the limit of two separated neutral subsystems, correctly reproduce the van der Waals R y6 behavior. We have calculated the corresponding van der Waals coefficient