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Validation of techniques for fast response measurement of HNO3 and NH3 and determination of the [NH3] [HNO3] concentration product

✍ Scribed by Harrison, Roy M; Msibi, I.M

Book ID
123216446
Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
744 KB
Volume
28
Category
Article
ISSN
1352-2310

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πŸ“œ SIMILAR VOLUMES

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The rate constant of the reaction, OH + NH3 -+ Hz0 + NH2, has been measured at temperatures between 230 and 490'K using time-resolved resonance absorption to observe the concemytion of OH radicals..An Arrhenius expression, kI = 2.3 X lO\_" exp(-1.6 kcai mole-'/RT) cm3 molecule-' set , was obtained.

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The mechanism for production of ekctronically excited photofragments from the title molecules is investigated using two excimer lasers in a pump-probe experiment. We find for NH(A) from NH3. N2H4 and CH3NH2; OH(A) from HN03 and CN(B) and CH(A. B) from CH;NH, that secondary excitation of primary phot